Orbital Symmetry and Electron Correlation inNaxCoO2

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Orbital symmetry and electron correlation in NaxCoO2.

Measurements of polarization-dependent soft x-ray absorption reveal that the electronic states determining the low-energy excitations of NaxCoO2 have predominantly a(1g) symmetry with significant O 2p character. In contrast to the prediction of band theory, doping-dependent O 1s x-ray absorption shows a large transfer of spectral weight, providing spectral evidence for strong electron correlati...

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ژورنال

عنوان ژورنال: Physical Review Letters

سال: 2005

ISSN: 0031-9007,1079-7114

DOI: 10.1103/physrevlett.94.146402